there is always weight in the valve train, but i see your point. OHC engines are easier to rev than OHV engines, in general. but there are also many more variables than the valve train that makes an engine easy to rev. for example, friction on the bottom end, stroke length, rod length, piston weight etc. etc.
for both types of engines, the lighter the part, the easier you can make it spin very fast. there are a few other types of motion in an internal combustion engine that apply also, but i forgot them...